Theory of the observed ultralow friction between sliding polyelectrolyte brushes

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Theory of the observed ultralow friction between sliding polyelectrolyte brushes.

It is shown using a method based on a modified version of the mean field theory of Miklavic and Marcelja [J. Phys. Chem. 92, 6718 (1988)] that it should be possible for osmotic pressure due to the counterions associated with the two polyelectrolyte polymer brush coated surfaces to support a reasonable load (i.e., about 10(6) Pa) with the brushes held sufficiently far apart to prevent entangleme...

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 2008

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.2948412